Document Type
Article
Publication Date
2003
Abstract
A dinuclear cobalt complex bearing the ligand bis(3-(2-pyridylmethyleneamino)phenyl) sulfone (BPMAPS) was prepared. It is proposed that the structure of this is [Coz(BPMAPS)(m-0AcMhemi-Et)]PF6 wherein the cobalt centers are bridged by two carboxylato groups in m-fashion and a hemiacetal with an ethoxy group (hemi-Et). This proposal is based on the similarity of the FT-IR, UV-Vis, and FAB-MS results with the crystallographically characterized dinuclear manganese complex [Mn2(BPMAPS)(m-OAcMhemi-Me)]PF6, and elemental analysis results.
Recommended Citation
Guidote, Armando M. Jr; Imajo, Tomoko; Kurusu, Yasuhiko; and Masuyama, Yoshiro, (2003). Possible Cobalt-Cobalt Bridging by a Hemiacetal in the Dinuclear Cobalt Complex Bearing the Ligand Bis(3-(2-pyridylmethyleneamino)phenyl) Sulfone. Archīum.ATENEO.
https://archium.ateneo.edu/chemistry-faculty-pubs/49